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Valued Member
United States
117 Posts |
Hi all, Following up on my last post where I had a few counterfeit 8 reales XRF tested, here are some results for an 1812 and 1813 Zacatecas 8 reales. For the 1812 I get a specific gravity result of 10.7 and 10.1 for the 1813. I was surprised to not see a gold trace, but maybe this particular XRF analyzer is not telling the whole story since the SGs are both noticeably different than 10.3.   1812 result:  1813 result:  Edited by threefifty 10/04/2023 5:39 pm
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Pillar of the Community
United States
1805 Posts |
10.7 seems too much to me.
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Pillar of the Community
United States
1932 Posts |
Well, either the SG calculations are off or those readouts don't perfectly reflect the alloy contents of either coin... or a little of both. Especially true for the 1812.
Edited by realeswatcher 10/04/2023 6:56 pm
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Pillar of the Community
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4326 Posts |
Remember, SG is the whole coin. XRF is just the small bit hit by the beam.
-----Burton 50 year / Life / Emeritus ANA member (joined 12/1/1973) Life member: Numismatics International, CONECA Member: TNA, FtWCC, NETCC, OnLine Coin Club Owned by four cats and a wife of 40 years (joined 1983)
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Valued Member
 United States
117 Posts |
Well shoot, I redid the SG test on the 1812 and now get 10.1. I also redid it on an 1807 from my collection and got 10.3, same as before.... so I must have been in a hurry or something when I measured the 1812.
The lead trace in the XRF results is interesting to me as I have not seen that discussed previously. I do wonder if there is a gold trace as well but the unit wasn't sensitive enough? I'll see if I can get a few more coins tested in the next month or so, and maybe retest some other ones to check consistency of the results.
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Pillar of the Community
United States
1788 Posts |
Please keep us posted when you get the new XRF readouts. By the way, very nice 1812, that coin is hard to find where it can even be identified.
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Moderator
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16181 Posts |
The heavier the element, the more sensitive XRF is to detecting it. Gold is a very heavy element, just slightly below lead on the periodic table, so this machine ought to be as sensitive to gold as it is to lead. It should easily be able to detect gold in the ppm levels; whether it's programmed to report gold levels that low is another question.
Don't say "infinitely" when you mean "very"; otherwise, you'll have no word left when you want to talk about something really infinite. - C. S. Lewis
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Pillar of the Community
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6896 Posts |
Agree ... the instrument should be capable for Au. Personally, I would always take an XRF result over SG, though (as pointed out by others) would take several XRF measurements.
Regardless, interesting results, thanks for sharing.
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Pillar of the Community
United States
1932 Posts |
Quote: By the way, very nice 1812, that coin is hard to find where it can even be identified. You know, I was kind of scratching my head a bit about you saying this... but it just occurred to me that this is the PROPER bust 1812 Zacatecas. A good bit scarcer than the 1812 Zac. armored bust and usually found horribly struck AND heavily worn.
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Valued Member
 United States
117 Posts |
Quote:
Please keep us posted when you get the new XRF readouts. By the way, very nice 1812, that coin is hard to find where it can even be identified.
Thank you! Before I bought it I briefly thought of holding out for a better condition piece, but I had read Max Keech's article describing the 1812 draped bust as "rock bottom" for quality of Zacatecas output, lol. So I'm glad I picked it up as a better one sounds hard to come by and likely would be priced accordingly. Thanks all for the XRF input. I haven't had a ton of coins tested so far, I'm interested to see more results. Not sure if the testing is rigorous enough to draw any concrete conclusions but I'm havimg fun.
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Pillar of the Community
United States
675 Posts |
Gosh, war of independence is perhaps more difficult than revolution coinage. CCs are ramped. XRF is cool but its just a bit of the surface. Know how the the coin is made, learned the hard way.
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Pillar of the Community
United States
5361 Posts |
Based on over 200 XRF tests run to date, I believe the necessity of a gold trace cannot be avoided on coins minted in Mexico. The parameters for Peru and Bolivia are different but can also be identified. SG along with XRF is critical as long as good lab procedures are in place. I learned how to do SG in High School and it has not changed in the 60 plus years since. The entire mother lode and adjacent veins in Mexico all have a detectable amount of gold in them. The denser metals are definitely easier to detect than the lighter ones. These are all simple scientific facts. These are published in articles and books on authentication.
A coin made in 1812 in Mexico has to contain gold. It comes with the silver period.
Now lead is a horse of a different color. Argentiferous lead is quite rare in Mexico. It is very common, in fact normal, for deposits in the UK and Europe to be argentiferous lead. Check when and where the Mexican deposits of this type were being refined and you will see that none are identified as early as 1812. The signature of the alloy may indicate an English numismatic forgery. Either or both could be.
Regarding a higher-than-expected SG, I have seen revolutionary era coins at 10.4 but none higher in my experience doing tests. I have heard of coins as high as 10-12% gold but I have not personally tested any of these. It is however theoretically possible based on modern core sample test results to find deposits that would be that high.
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Pillar of the Community
United States
1702 Posts |
UPDATE: Actually I expect both of these pieces to be regal issues. An XRF gun has limitations and since the gold signature in most period pieces are >0.1% and <1.0% an XRF gun as you mention may not always picks up Au at this quantitative level. NO CONCERN. Additionally at this mint I also expect silver values not always to be pegged at 90%. An XRF gun has limitations as with reporting Iridium values which do not exist as in Larry Schmidt's Davignon Bust Half XRF Assay databases and having a recent JEAN ANS William III CCC article debunked as being nothing more than Iridium false positive results. We need to be VERY CONSERVATIVE in our thoughts with XRF Gun Assay's. As I said these are regals IMO. Not CCCs. A higher end Material Analysis may prove me wrong - but I doubt it. John Lorenzo, Numismatist.
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